气凝胶功能复合材料


围绕气凝胶功能复合材料开展了系统研究,实现了多种气凝胶复合材料的可控构筑,包括聚合物复合气凝胶、纳米纤维气凝胶、气凝胶纤维/织物以及碳气凝胶等,并探索了其在隔热阻燃、智能热管理、电磁屏蔽与吸收、能源存储与转换等领域的应用,为高性能及多功能一体化的新型气凝胶复合体系的设计和研发奠定了坚实基础

 

1. 轻质隔热聚合物基复合气凝胶


针对目前气凝胶材料存在成型差、收缩率高、孔结构不可控、强度低等问题,本课题组创新性地提出了聚合物气凝胶三维结构构筑与孔结构调控的新策略,实现了轻质高强、高柔弹性的聚酰亚胺气凝胶复合材料的可控制备,获得了具有优异隔热阻燃性能的气凝胶复合材料

 

2. 智能热管理气凝胶纤维及织物


针对目前气凝胶纤维存在成型困难、力学强度差、功能单一等问题,本课题组创新性地提出“湿法-冷冻纺丝”、“紫外辅助快速凝胶”等纤维成型新策略 ,获得了轻质、高强、隔热高分子复合气凝胶纤维;进一步对高分子复合气凝胶纤维/织物进行功能化处理,构建了高性能的新型智能热管理织物


3. 电磁吸收气凝胶材料


针对目前气凝胶电磁吸收强度弱、频带窄、频段单一和耐候性差等问题,本课题组创新性地提出“多层自组装” 新策略,成功获得具有多级阻抗结构宽频吸波和“碳包铁”耐候性吸波性能的气凝胶复合材料。

   

代表性论文:

1. H. L. Guo, J. Zhou, Q. Q. Li, Y. M. Li, W. Zong, J. X. Zhu, J. S. Xu, C. Zhang*, T. X. Liu*. Emerging dual-channel transition-metal-oxide quasiaerogels by self-embedded templating. Adv. Funct. Mater. 2020, 30, 2000024.

2. Y. J. Wang, Y. Cui, Z. Y. Shao, W. W. Gao, W. Fan*, T. X. Liu, H. Bai*. Multifunctional polyimide aerogel textile inspired by polar bear hair for thermoregulation in extreme environments. Chem. Eng. J. 2020, 390, 124623.

3. X. Zhang, X. Y. Zhao, T. T. Xue, F. Yang, W. Fan*, T. X. Liu*. Bidirectional anisotropic polyimide/bacterial cellulose aerogels by freeze-drying for super-thermal insulation. Chem. Eng. J. 2020, 385, 123963.

4. X. Y. Zhao, F. Yang, Z. C. Wang, P. M. Ma, W. F. Dong, H. Q. Hou, W. Fan*, T. X. Liu*. Mechanically strong and thermally insulating polyimide aerogels by homogeneity reinforcement of electrospun nanofibers. Compos. Part B 2020, 182, 107624.

5. H. L. Guo, Q. C. Feng, K. W. Xu, J. S. Xu, J. X. Zhu, C. Zhang*, T. X. Liu*. Self-templated conversion of metallogel into heterostructured TMP@carbon quasi-aerogels boosting bifunctional electrocatalysis. Adv. Funct. Mater. 2019, 29, 1903660.

6. D. Wang, W. Fan*, S. J. Yuan, T. X. Liu*, Improving hierarchical porous structure of carbon aerogels for more efficient ion transport for supercapacitors with commercial level mass loading. Electrochim. Acta 2019, 323, 134811.

7. W. Fan, X. Zhang, Y. Zhang, Y. F. Zhang, T. X. Liu*. Lightweight, strong, and super-thermal insulating polyimide composite aerogels under high temperature. Compos. Sci. Technol. 2019, 173, 47-52.

8. Y. F. Zhang, W. Fan*, H. Y. Lu, T. X. Liu*, Highly porous polyimide-derived carbon aerogel as advanced three-dimensional framework of electrode materials for high-performance supercapacitors, Electrochim. Acta 2018, 283, 1763-1772.

9. W. Fan, L. Z. Zuo, Y. F. Zhang, Y. Chen*, T. X. Liu*. Mechanically strong polyimide / carbon nanotube composite aerogels with controllable porous structure, Compos. Sci. Technol. 2018, 156, 186-191.

10. Z. C. Wang, R. B. Wei, J. W. Gu, et al. Ultralight, highly compressible and fire-retardant graphene aerogel with self-adjustable electromagnetic wave absorption. Carbon 2018, 139, 1126-1135.

11. Z. C. Wang, R. B. Wei, X. B. Liu. Fluffy and ordered graphene multilayer films with improved electromagnetic interference shielding over x-band. ACS Appl. Mater. Interfaces 2017, 9, 22408-22419.

12. L. Z. Zuo, W. Fan*, Y. F. Zhang, L. S. Zhang, W. Gao, Y. P. Huang, T. X. Liu*. Graphene/montmorillonite hybrid synergistically reinforced polyimide composite aerogels with enhanced flame-retardant performance. Compos. Sci. Technol. 2017, 139, 57-63.

13. M. K. Liu, B. M. Liu, H. Zhou, C. Chen, Y. Q. Liu, T. X. Liu*. Extraordinary rate capability achieved by a 3D “skeleton/skin” carbon aerogel-polyaniline hybrid with vertically aligned pores. Chem. Commun. 2017, 53, 2810-2813.

14. L. Z. Zuo, Y. F. Zhang, Y. P. Huang, W. Gao, W. Fan*, T. X. Liu*. Bacterial cellulose-based graphene-like carbon aerogels for in-situ growth of nickel sulfide as high performance electrode materials for supercapacitors. Nanoscale 2017, 9, 4445-4455.

15. Z. Sun, W. Fan*, T. X. Liu*. Graphene/graphene nanoribbon aerogels as tunable three-dimensional framework for efficient hydrogen evolution reaction. Electrochimica Acta 2017, 250, 91-98.

16. Y. F. Zhang, L. Z. Zuo, Y. P. Huang, L. S. Zhang, F. L. Lai, W. Fan*, T. X. Liu*. Cotton wool derived carbon fiber aerogel supported few-layered MoSe2 nanosheets as efficient electrocatalysts for hydrogen evolution. ACS Appl. Mater. & Interfaces 2016, 8, 7077-7085.

17. Y. F. Zhang, L. Z. Zuo, L. S. Zhang, J. J. Yan, H. Y. Lu, W. Fan*, T. X. Liu*. Immobilization of NiS nanoparticles on N-doped carbon fiber aerogels as advanced electrode materials for supercapacitors. Nano Res. 2016, 9, 2747-2759.

18. F. L. Lai, L. Z. Zuo, H. H. Gu, Y. E. Miao*, T. X. Liu*. Electrospun nanofiber-supported carbon aerogel as a versatile platform toward asymmetric supercapacitors. J. Mater. Chem. A 2016, 4, 15861-15869.

19. M. K. Liu, Z. B. Yang, H. Sun, C. Lai, X. S. Zhao, H. S. Peng*, T. X. Liu*. A hybrid carbon aerogel with both aligned and interconnected pores as interlayer for high-performance lithium-sulfur batteries. Nano Res. 2016, 9, 3735-3746.

20. Y. F. Zhang, L. Z. Zuo, Y. P. Huang, L. S. Zhang, F. L. Lai, W. Fan*, T. X. Liu*. In-situ growth of few-layered MoS2 nanosheets on highly porous carbon aerogel as advanced electrocatalysts for hydrogen evolution reaction. ACS Sustain. Chem. Eng. 2015, 3, 3140-3148.


技术支持:信息化建设管理处

地址:江苏省无锡市蠡湖大道1800号

邮编:214122

联系我们:txliu@jiangnan.edu.cn